By K. L. Mittal (Eds.)
content material: Thermodynamics of adsorption and interparticle forces / D.H. Everett and C.J. Radke --
Configurational habit of remoted chain molecules adsorbed from athermal recommendations / M. Lal, M.A. Turpin, K.A. Richardson, and D. Spencer --
Equilibrium movie strain on a flat, low-energy sturdy / Robert J. solid --
Binding of solute and solvent on the interface and the gibbs floor extra / D.K. Chattoraj and S.P. Moulik --
Mechanism of sulfonate adsorption on the silver iodide-solution interface / okay. Osseo-Asare, D.W. Fuerstenau, and R.H. Ottewill --
Adsorption of dyes on water-swollen and non-swelling good substrates / S.R. Sivaraja Iyer, A.S. Chanekar, and G. Srinivasan --
Adsorption of polystyrene on graphon from toluene / Victor okay. Dunn and Robert D. Vold --
Adsorption of ionic surfactants to porous glass : the exclusion of micelles and different solutes from adsorbed layers and the matter of adsorption maxima / Pasupati Mukerjee and Aroonsri Anavil --
DTA research of water in porous glass / Chaur-Sun Ling and W. Drost-Hansen --
Monolayer reviews. five, Styrene-acrylic acid motion pictures on aqueous substrates / Erwin Sheppard and Noubar Tcheurekdjian --
interplay of calcium ions with the combined monolayers of stearic acid and stearyl alcohol at pH 8.8 / D.O. Shah --
touch angles in Newton-Black cleaning soap motion pictures drawn from recommendations containing sodium dodecyl sulphate and electrolyte / J.A. De Feijter and A. Vrij --
Stratification in unfastened liquid motion pictures / J.W. Keuskamp and J. Lyklema --
floor chemical houses of hugely fluorinated polymers / Marianne okay. Bernett and W.A. Zisman --
impression of floor oxygen complexes on floor habit of carbons / Balwant Rai Puri --
floor houses of nickel hydroxide earlier than and after dehydration to nickel oxide / M. subject, F.J. Micale, C.L. Cronan, H. Leidheiser, Jr., and A.C. Zettlemoyer --
The size of low interfacial pressure through the spinning drop procedure / J.L. Cayias, R.S. Schechter, and W.H. Wade --
Adhesion of ice frozen from dilute electrolyte options / H.H.G. Jellinek --
Mechanism of olfaction defined utilizing interfacial pressure measurements / D.V. Rathnamma --
position of double interactions and spreading strain in particulate soil elimination / Hermann Lange.
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Additional info for Adsorption at Interfaces
Ir has been reported to be large f o r low-boiling gases such as N on Teflon. Graham (4) noted a d i f f i c u l t y a r i s i n g from bulk s o l u b i l i t y of an alkane i n the substrate, such that the quantity sorbed could not be uniquely assigned as between adsorption and absorption. )). 7 erg/cm^, was an upper l i m i t ; he could not estimate the r e a l value. 3 f o r hexane and 2,9 for octane. They e x p l i c i t l y corrected for pendular r i n g condensation, and i n so doing, they obtained estimates of ir i n t h e i r systems that were very probably more v a l i d than Graham's were f o r h i s .
3. g. 1 f o r hexane i n the absence of step s i t e s . 5 for Teflon with step s i t e s accounting for 5% of the area, shows the d i r e c t i o n of change i n the computed r e s u l t s when a more complex surface i s postulated. The preliminary computations made f o r CCl^ indicate that the e x p l i c i t employment of a two-dimensional van der Waals equation (11,12) would be worthwhile with the lower hydrocarbons. We w i l l investigate such two-dimensional condensation i n another communication.
23 Isolated Chain Molecules The mean f r a c t i o n s o f segments b o u n d t o t h e s u r f a c e c a l c u l a t e d assuming various values o f segment/surface b i n d i n g e n e r g y a r e p r e s e n t e d i n f i g u r e 3. 5, l e s s t h a n 1 0 % o f t h e s e g m e n t s a r e a d s o r b e d , while a t -Δ62/ΚΤ 1·4, a p p r o x i m a t e l y 7 5 % o f t h e segments w o u l d be o n t h e s u r f a c e . The < V> v e r s u s - Δ ^ 2 ^ e x t r a p o l a t e d t o d e t e r m i n e t h e p o i n t b e l o w w h i c h < V> i s z e r o .